The Merseysiders defeated the London side in the League Cup Round of 16 (1–1, 6–5 on penalties).
In total, the Reds have secured five victories in penalty shootouts against the Blues: in the Champions League (2006/07 season), the UEFA Super Cup (2019/20), the League Cup (2021/22), the FA Cup (2021/22), and the League Cup (2026/27).
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